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Thomas J.J. Müller "Metal Catalyzed Cascade Reactions (Topics in Organometallic Chemistry, Volume 19)"

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience.

The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Transition metal-catalyzed cascade reactions are an elegant approach to complex molecular scaffolds. Besides their esthetics and increase in structural complexity, they have also become mechanistic challenges for the combination of organometallic elementary steps. As a consequence, cascade reactions have revolutionized synthetic strategies and conceptual thinking. The authors highlight cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael-type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. Therefore, the reader finds overview of an exciting and highly dynamic field of a new and innovative methodological concept.

Chapters of this Volume:

- Palladium-Catalyzed Cyclization via Carbopalladation and Acylpalladation

- Domino Heck-Pericyclic Reactions

- Palladium Catalyzed Cascade Reactions Involving π-Allyl Palladium Chemistry

- The Virtue of Michael-Type Addition Processes in the Design of Transition Metal-Promoted Cyclizative Cascade Reactions

- Sequentially Palladium-Catalyzed Processes

- Cascade Reactions Involving Pauson–Khand and Related Processes

- Complex Polycyclic Molecules from Acyclic Precursors via Transition Metal-Catalyzed Cascade Reactions

- Cascade and Sequential Catalytic Transformations Initiated by Ruthenium Catalysts

Written for:

Academic and industrial researchers in organometallics, organic chemistry, inorganic chemistry, pharmaceutical and medicinal chemistry

Keywords:

- Catalysis

- Organometallic Chemistry

- Inorganic Chemistry

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