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Karl Heinz Dötz "Metal Carbenes in Organic Synthesis (Topics in Organometallic Chemistry, Volume 13)"

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience.

The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Metal carbene complexes have made their way from organometallic curiosities to valuable reagents and catalysts. They offer novel synthetic opportunities in carbon carbon bond formation based on either carbene-centered reactions or on metal-templated processes which makes them indispensable in modern synthetic methodology. The most prominent metal carbenes are now either commercially available or easy to synthesize and handle by modern laboratory techniques. This volume organized in eight chapters written by the leading scientists in the field illustrates the theoretical background, non-classical nucleophilic and cycloaddition patterns, chromium-templated benzannulation and photo-induced reactions, rhodium-catalyzed carbene transfer as well as the principles and applications of olefin metathesis which coined the progress in synthetic methodology over the past decade. Designed for researchers in academia and industry as well as graduate students it presents the state-of-the-art potential of carbene complexes in modern organic synthesis.

Chapters of this Volume:

- Electronic Structure and Reactivity of Metal Carbenes

- The Multifaceted Chemistry of Variously Substituted a,ß-Unsaturated Fischer Metalcarbenes

- Cycloaddition Reactions of Group 6 Fischer Carbene Complexes

- Chromium-Templated Benzannulation Reactions

- Photoinduced Reactions of Metal Carbenes in Organic Synthesis

- Metal Carbene Reactions from Dirhodium(II) Catalysts

- Olefin Metathesis Directed to Organic Synthesis: Principles and Applications

- Diene, Enyne, and Diyne Metathesis in Natural Product Synthesis

Written for:

Academic and industrial researchers in organometallics, organic chemistry, inorganic chemistry, pharmaceutical and medicinal chemistry.

Keywords:

- Inorganic Chemistry

- Medicinal Chemistry

- Organic Chemistry

- Organometallic Chemisty

- Pharmaceutical Chemistry

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