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Technology of Fluoropolymers, Second Edition By Jiri George Drobny

Fully revised and updated, this second edition continues to provide industrial chemists, technologists, and engineers with the most accurate, compact, and practical source on fluoropolymers (such as Teflon).

Highlighting new industrial, military, medical, and consumer goods applications, this edition adds more detailed information on equipment and processing conditions. It explores breakthroughs in understanding property-structure relationships, new polymerization techniques, and the chemistry underlying novel polymers, such as melt-processable fluoroplastics. It also expands upon critical environmental aspects of fluoropolymers, including heat degradation, health effects, and recycling.

Contents

Preface to the First Edition .................................................................................... xiii

Preface to the Second Edition ..................................................................................xv

Acknowledgments ..................................................................................................xvii

About the Author ....................................................................................................xix

Chapter 1 Introduction ..........................................................................................1

Chapter 2 Basic Chemistry of Fluoropolymers .....................................................7

2.1 Polytetrafluoroethylene ...................................................................................7

2.1.1 Industrial Synthesis of Tetrafluoroethylene ........................................7

2.1.2 Properties of Tetrafluoroethylene .......................................................8

2.1.3 Uses of Tetrafluoroethylene ................................................................9

2.1.4 Polymerization of Tetrafluoroethylene ...............................................9

2.2 Fluorinated Ethylene Propylene (FEP) ......................................................... 13

2.2.1 Industrial Synthesis of HFP .............................................................. 13

2.2.2 Properties of HFP ............................................................................. 13

2.2.3 Industrial Process for the Production of FEP ................................... 14

2.3 Perfluoroalkoxy (PFA) Resin ........................................................................ 14

2.3.1 Industrial Synthesis of Perfluoroalkyl Vinyl Ether Monomers ........ 14

2.3.2 Properties of Perfluoroalkylvinyl Ethers .......................................... 15

2.3.3 Industrial Process for the Production of Perfluoroalkoxy Resins ..... 15

2.4 Polychlorotrifluoroethylene (PCTFE) ........................................................... 15

2.4.1 Industrial Synthesis of Chlorotrifluoroethylene Monomer ............... 15

2.4.2 Properties of CTFE ........................................................................... 15

2.4.3 Industrial Process for the Production of PCTFE .............................. 16

2.5 Polyvinylidene Fluoride (PVDF) .................................................................. 16

2.5.1 Industrial Synthesis of Vinylidene Fluoride Monomer .................... 16

2.5.2 Properties of Vinylidene Fluoride .................................................... 17

2.5.3 Industrial Process for the Production of PVDF ................................ 17

2.6 Polyvinyl Fluoride (PVF) .............................................................................. 18

2.6.1 Industrial Synthesis of Vinyl Fluoride (VF) Monomer .................... 18

2.6.2 Industrial Process for the Production of PVF ................................... 18

2.7 Ethylene Chlorotrifluoroethylene (ECTFE) Copolymer ............................... 18

2.7.1 Industrial Process for the Production of ECTFE .............................. 18

2.8 Ethylene Tetrafluoroethylene (ETFE) Copolymer ........................................ 19

2.8.1 Industrial Process for the Production of ETFE ................................ 19

2.9 Terpolymers of TFE, HFP, and VDF (THV Fluoroplastic) .......................... 19

2.10 Terpolymers of HFP, TFE, and Ethylene (Hexafluoropropylene,

Tetrafluoroethylene, and Ethylene Fluoroplastic) ..........................................20

... etc

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