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Supramolecular Polymers, Second Edition Edited by Alberto Ciferri (2004)

* Introduces supramolecular interactions and dynamic association-dissociation processes

* Covers properties and applications of self-assembled, reversible structures including linear, helical, columnar, tubular polymers, micelles, monolayers, three-dimensional phases, and networks

* Describes stabilized assemblies such as covalently bonded polymers exhibiting novel supramolecular effects, polymers with mechanically interlocked units, dendrimers, and monolayers

* Details host-guest composites mimicking biological systems, and engineered assemblies such as layered polyelectrolytes

Supramolecular Polymers, Second Edition details assembly processes and structure-function correlation in natural and synthetic self-assembling materials, focusing on developments occurred over the past five years.

The book highlights developments in the synthesis of complex structures, chemical design principles, and theoretical models of growth processes resulting in an increasingly accurate prediction of stability, degree of polymerization, and shape of various assemblies. It focuses on the rich variety of properties, functions, and applications of self-assembling supramolecular polymers. Supramolecular Polymers, Second Edition ties together potential applications such as those of nanostructures with dynamic-combinatorial-adaptive self-healing features, opto-electronic devices, supramolecular amphiphiles, hydrogels, organic/inorganic nanocomposites, molecular biosensors, molecular imprinting, molecular engines, templates for superlattices with prescribed symmetry. Several chapters of the first edition have been updated or rewritten, and an equal number of new chapters have been added. More than 500 drawings, photographs, micrographs, equations, and tables enhance and reinforce essential concepts presented in the book

Authored by an expert in polymer mechanics, biopolymers, liquid crystals, and supramolecular assemblies, Supramolecular Polymers, Second Edition emphasizes fundamental principles at the basis of bottom-up nanotechnology , chemical design strategies, and exciting applications for various self-assembling materials for a unified and cutting-edge account of the field.

Contents

PART I: THEORY AND STRUCTURE

Supramolecular Polymer Chemistry -Scope and Perspectives; J.-M. Lehn

Growth of Supramolecular Structures; A. Ciferri

Theory of Supramolecular Polymerization; P. van der Schoot

Supramolecular Liquid Crystals: Simulation; R. Hentschke, P. Lenz, and B. Fodi

Supramolecular Low-Molecular Weight Complexes and Supramolecular Side-Chain Polymers; T. Kato

Hydrogen-Bonded Supramolecular Polymers: Linear and Network Polymers and Self-Assembling Discotic Polymers; P.S. Corbin and S.C. Zimmermann

Dendrimeric Supramolecular and Supramacromolecular Assemblies; D.A. Tomalia

Polymers with Interwined Superstructures and Interlocked Structures; J. B. Beck and S.J. Rowan

Theory of Block Copolymers; M.D. Whitmore

Assemblies in Complex Block Copolymer Systems; V. Abetz

Microstructure and Crystallization of Rigid-Coil Comblike Polymers and Block Copolymers; K. Loos and S. Muñoz-Guerra

PART II: PROPERTIES AND FUNCTIONS

DNA Structures and their Applications in Nanotechnology; J. Xu, T.H. LaBean, and S.L. Craig

Soluble Amphiphilic Nanostructures and Potential Applications; N. Kimizuka

Supramolecular Properties of Polymers for Plastic Electronics; D. Comoretto

Supramolecular Polymers in Action; A.W. Bosman and R.P. Sijbesma

Columnar, Helical, and Tubular Supramolecular Polymers; W. Zhang and C. Nuckolls

Crystalline Bacterial Cell Surface Layers (S-Layers): A Versatile Self-Assembly System; U.B. Sleytr, M. Sára, D. Pum, and B. Schuster

Self-Assembled Monolayers (SAMs) and Synthesis of Planar Micro- and Nanostructures; L. Yan, Wilhelm T.S. Huck, and G.M. Whitesides

Layered Polyelectrolyte Assemblies; X. Arys, A.M. Jonas, A. Laschewsky, R. Legras, and F. Mallwitz

Molecular Imprinting; M. Komiyama

Protein Polymerization and Polymer Dynamics Approach to Functional Systems; F. Oosawa

Force Generation by Cellular Polymers; G. Oster and A. Mogilner

Index

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