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"The Properties of Gases and Liquids, Fifth Edition" by Bruce E. Poling, John M. Prausnitz, John P. O'Connell

Must-have reference for processes involving liquids, gases, and mixturesReap the time-saving, mistake-avoiding benefits enjoyed by thousands of chemical and process design engineers, research scientists, and educators. Properties of Gases and Liquids, Fifth Edition, is an all-inclusive, critical survey of the most reliable estimating methods in use today --now completely rewritten and reorganized by Bruce Poling, John Prausnitz, and John O'Connell to reflect every late-breaking development. You get on-the-spot information for estimating both physical and thermodynamic properties in the absence of experimental data with this property data bank of 600+ compound constants. Bridge the gap between theory and practice with this trusted, irreplaceable, and expert-authored expert guide -- the only book that includes a critical analysis of existing methods as well as hands-on practical recommendations. Areas covered include pure component constants; thermodynamic properties of ideal gases, pure components and mixture; pressure-volume-temperature relationships; vapor pressures and enthalpies of vaporization of pure fluids; fluid phase equilibria in multicomponent systems; viscosity; thermal conductivity;diffusion coefficients; and surface tension.

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CONTENTS

Preface

Chapter 1 The Estimation of Physical Properties 1.1

1-1 Introduction / 1.1

1-2 Estimation of Properties / 1.3

1-3 Types of Estimation / 1.3

1-4 Organization of the Book / 1.6

Chapter 2 Pure Component Constants 2.1

2-1 Scope / 2.1

2-2 Vapor-Liquid Critical Properties / 2.2

2-3 Acentric Factor / 2.23

2-4 Boiling and Freezing Points / 2.26

2-5 Discussion of Estimation Methods for Pure Component Constants / 2.33

2-6 Dipole Moments / 2.34

2-7 Availability of Data and Computer Software / 2.35

Chapter 3 Thermodynamic Properties of Ideal Gases 3.1

3-1 Scope and Definitions / 3.1

3-2 Estimation Methods / 3.5

3-3 Method of Joback / 3.6

3-4 Method of Constantinou and Gani (CG) / 3.8

3-5 Method of Benson [1968; 1969] / 3.14

3-6 Discussion and Recommendations / 3.46

3-7 Heat of Combustion / 3.47

Chapter 4 Pressure-Volume-Temperature Relationships of Pure Gases and Liquids 4.1

4-1 Scope / 4.1

4-2 Introduction to Volumetric Properties / 4.1

4-3 Corresponding States Principle / 4.5

4-4 Equations of State / 4.8

4-5 Virial Equation of State / 4.11

4-6 Analytical Equations of State / 4.17

4-7 Nonanalytic Equations of State / 4.25

4-8 Discussion of Equations of State / 4.31

4-9 PVT Properties of Liquids—General Considerations / 4.32

4-10 Estimation of the Liquid Molar Volume at the Normal Boiling Point / 4.33

4-11 Saturated Liquid Densities as a Function of Temperature / 4.35

4-12 Compressed Liquid Densities / 4.43

Chapter 5 Pressure-Volume-Temperature Relationships of Mixtures 5.1

5-1 Scope / 5.1

5-2 Mixture Properties—General Discussion / 5.2

5-3 Corresponding States Principle (CSP): The Pseudocritical Method / 5.5

5-4 Virial Equations of State for Mixtures / 5.8

5-5 Analytical Equations of State for Mixtures / 5.12

5-6 Nonanalytic Equations of State for Mixtures / 5.18

5-7 Discussion of Mixture Equations of State / 5.22

5-8 Densities of Liquid Mixtures at Their Bubble Point / 5.23

5-9 Densities of Compressed Liquid Mixtures / 5.26

Chapter 6 Thermodynamic Properties of Pure Components and Mixtures 6.1

6-1 Scope / 6.1

6-2 Fundamental Thermodynamic Relationships for Pure Components / 6.1

6-3 Departure Functions for Thermodynamic Properties / 6.4

6-4 Evaluation of Departure Functions for Equations of State / 6.6

6-5 Heat Capacities of Real Gases / 6.16

6-6 Heat Capacities of Liquids / 6.17

6-7 Partial Properties and Fugacities of Components in Mixtures / 6.26

6-8 True Critical Points of Mixtures / 6.30

Chapter 7 Vapor Pressures and Enthalpies of Vaporization of Pure Fluids 7.1

7-1 Scope / 7.1

7-2 Theory / 7.1

7-3 Correlation and Extrapolation of Vapor-Pressure Data / 7.3

7-4 Ambrose-Walton Corresponding-States Method / 7.7

7-5 Riedel Corresponding-States Method / 7.9

7-6 Discussion and Recommendations for Vapor-Pressure Estimation and

Correlation / 7.11

7-7 Enthalpy of Vaporization of Pure Compounds / 7.13

7-8 Estimation of Hv from Vapor-Pressure Equations / 7.14

7-9 Estimation of Hv from the Law of Corresponding States / 7.16

7-10 Hv at the Normal Boiling Point / 7.19

7-11 Variation of Hv with Temperature / 7.23

7-12 Discussion and Recommendations for Enthalpy of Vaporization / 7.24

7-13 Enthalpy of Fusion / 7.25

7-14 Enthalpy of Sublimation; Vapor Pressures of Solids / 7.28

Chapter 8 Fluid Phase Equilibria in Multicomponent Systems 8.1

8-1 Scope / 8.1

8-2 Thermodynamics of Vapor-Liquid Equilibria / 8.9

8-3 Fugacity of a Pure Liquid / 8.11

8-4 Simplifications in the Vapor-Liquid Equilibrium Relation / 8.12

8-5 Activity Coefficients; Gibbs-Duham Equation and Excess Gibbs Energy / 8.12

8-6 Calculation of Low-Pressure Binary Vapor-Liquid Equilibria with Activity Coefficients / 8.19

8-7 Effect of Temperature on Low-Pressure Vapor-Liquid Equilibria / 8.22

8-8 Binary Vapor-Liquid Equilibria: Low-Pressure Examples / 8.23

8-9 Multicomponent Vapor-Liquid Equilibria at Low Pressure / 8.32

8-10 Determination of Activity Coefficients / 8.42

8-11 Phase Equilibrium with Henry’s Law / 8.111

8-12 Vapor-Liquid Equilibria with Equations of State / 8.120

8-13 Solubilities of Solids in High-Pressure Gases / 8.158

8-14 Liquid-Liquid Equilibria / 8.159

8-15 Phase Equilibria in Polymer Solutions / 8.177

8-16 Solubilities of Solids in Liquids / 8.180

8-17 Aqueous Solutions of Electrolytes / 8.191

8-18 Concluding Remarks / 8.193

Chapter 9 Viscosity 9.1

9-1 Scope / 9.1

9-2 Definitions of Units of Viscosity / 9.1

9-3 Theory of Gas Transport Properties / 9.2

9-4 Estimation of Low-Pressure Gas Viscosity / 9.4

9-5 Viscosities of Gas Mixtures at Low Pressures / 9.15

9-6 Effect of Pressure on the Viscosity of Pure Gases / 9.29

9-7 Viscosity of Gas Mixtures at High Pressures / 9.47

9-8 Liquid Viscosity / 9.51

9-9 Effect of High Pressure on Liquid Viscosity / 9.55

9-10 Effect of Temperature on Liquid Viscosity / 9.56

9-11 Estimation of Low-Temperature Liquid Viscosity / 9.59

9-12 Estimation of Liquid Viscosity at High Temperatures / 9.75

9-13 Liquid Mixture Viscosity / 9.77

Chapter 10 Thermal Conductivity 10.1

10-1 Scope / 10.1

10-2 Theory of Thermal Conductivity / 10.1

10-3 Thermal Conductivities of Polyatomic Gases / 10.2

10-4 Effect of Temperature on the Low-Pressure Thermal Conductivities of Gases / 10.18

10-5 Effect of Pressure on the Thermal Conductivities of Gases / 10.18

10-6 Thermal Conductivities of Low-Pressure Gas Mixtures / 10.29

10-7 Thermal Conductivities of Gas Mixtures at High Pressures / 10.35

10-8 Thermal Conductivities of Liquids / 10.42

10-9 Estimation of the Thermal Conductivities of Pure Liquids / 10.44

10-10 Effect of Temperature on the Thermal Conductivities of Liquids / 10.51

10-11 Effect of Pressure on the Thermal Conductivities of Liquids / 10.52

10-12 Thermal Conductivities of Liquid Mixtures / 10.56

Chapter 11 Diffusion Coefficients 11.1

11-1 Scope / 11.1

11-2 Basic Concepts and Definitions / 11.1

11-3 Diffusion Coefficients for Binary Gas Systems at Low Pressures: Prediction from Theory / 11.5

11-4 Diffusion Coefficients for Binary Gas Systems at Low Pressures: Empirical Correlations / 11.9

11-5 The Effect of Pressure on the Binary Diffusion Coefficients of Gases / 11.12

11-6 The Effect of Temperature on Diffusion in Gases / 11.19

11-7 Diffusion in Multicomponent Gas Mixtures / 11.19

11-8 Diffusion in Liquids: Theory / 11.20

11-9 Estimation of Binary Liquid Diffusion Coefficients at Infinite Dilution / 11.21

11-10 Concentration Dependence of Binary Liquid Diffusion Coefficients / 11.33

11-11 The Effects of Temperature and Pressure on Diffusion in Liquids / 11.38

11-12 Diffusion in Multicomponent Liquid Mixtures / 11.41

11-13 Diffusion in Electrolyte Solutions / 11.43

Chapter 12 Surface Tension 12.1

12-1 Scope / 12.1

12-2 Introduction / 12.1

12-3 Estimation of Pure-Liquid Surface Tension / 12.2

12-4 Variation of Pure-Liquid Surface Tension with Temperature / 12.11

12-5 Surface Tensions of Mixtures / 12.12

Appendix A Property Data Bank A.1

Appendix B Lennard-Jones Potentials as Determined from Viscosity Data B.1

Appendix C Group Contributions for Multiproperty Methods C.1

Index follows Appendix C

with TOC BookMarkLinks

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