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Polymer Modification edited by Graham Swift, Charles E. Carraher, Jr., and Christopher N. Bowman

Eighteen papers from an August 1996 conference in Orlando, Florida address the development of new modified polymeric materials for a variety of specialty applications that use the chemistry-on-polymers approach. Subject areas include grafting and chemical oxidation, inorganic-containing and shaped polymers, various chemical modifications, and reactions

Surface Modifications

The Preparation of Methyl Methacrylate/Methacrylic Anhydride

Copolymers from PMMA and Dialkyl Amines via Reaction

Extrusion ............................................................................................ 3

Grafting of Hindered Amine Groups on EPDM and Polyoctenamer

via Photo-Hydroperoxidation ............................................................. 11

Reactive Gases as Reagents for Polymer Films Chemical

Modifications ...................................................................................... 21

The Synthesis of Hydrophobe-Modified Hydroxyethyl Cellulose

Polymers Using Phase Transfer Catalysis ........................................ 31

The Synthesis and Characterization of Polyesters Derived from LLactide

and Variably-Sized Poly(Caprolactone) ................................ 45

Reactions with Vinyl Polymers

The Functionalization of Polyolefms by Using Reactive

Intermediates ..................................................................................... 61

Chemical Modification of Acrylamide Polymers in Aqueous

Solution .............................................................................................. 77

Synthesis and Characterization of Poly(Magnesium Acrylate) and

Poly(Zirconyl Acrylate) towards the Formation of Magnesium

Partially Stabilized Zirconia Ceramics ............................................... 85

Preparation of Functionalized Polymers by Reactions of

Poly(Vinylbenzyl Chloride) ................................................................. 97

Graft Copolymerization of Vinyl Monomers onto Polymers

Containing Styrene ............................................................................ 109

Chemical Cross-Linking by Glutaraldehyde between Amino Groups:

Its Mechanism and Effects ................................................................. 119

Poly(Chlorotrifluoroethylene) Substituted Reactions ............................... 133

Inorganic-Containing and Shaped Polymers

Synthesis and Structural Characterization of Inorganic Tin

Ionomers ............................................................................................ 155

Computer Modeling of Poly(Acrylic Acid) and Its Salts ............................ 165

Synthesis and Structural Characterization of Titanocene-Containing

Polyethers Based on Reaction with Ethylene Oxide-Containing

Diols, Including Polyethylene Glycol) ................................................. 171

Synthesis of Novel Silanol Polymers and Copolymers by a Selective

Oxidation of Si – H Bond from Corresponding Precursor

Polymers ............................................................................................ 179

Synthesis and Ion-Coupling Reactions of Telechelic

Poly(Dimethylsiloxane) Having Cyclic Onium Salt Groups ................ 187

An Empirical and Modeling Study of Boron Speciation in Solution

with a Reactive Dendrimeric Polymer ................................................ 197

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