Science/Engineering Phase Transitions in Polymers: The Role of Metastable States (0444519114)

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Phase Transitions in Polymers: The Role of Metastable States

A classical metastable state possesses a local free energy minimum at infinite sizes, but not a global one. This concept is phase size independent. We have studied a number of experimental results and proposed a new concept that there exists a wide range of metastable states in polymers on different length scales where their metastability is critically determined by the phase size and dimensionality. Metastable states are also observed in phase transformations that are kinetically impeded on the pathway to thermodynamic equilibrium. This was illustrated in structural and morphological investigations of crystallization and mesophase transitions, liquid-liquid phase separation, vitrification and gel formation, as well as combinations of these transformation processes. The phase behaviours in polymers are thus dominated by interlinks of metastable states on different length scales. This concept successfully explains many experimental observations and provides a new way to connect different aspects of polymer physics.

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	Science/Engineering Phase Transitions and Renormalisation Group Jean Zinn-Justin “Phase Transitions and Renormalisation Group " Oxford University Press, USA \| 2007-08-30 \| ISBN: 0199227195 \| 464 pages \| PDF \| 3,2 Mb
	Science/Engineering Non-Equilibrium Phase Transitions: Volume 1: Absorbing Phase Transitions Non-Equilibrium Phase Transitions: Volume 1: Absorbing Phase TransitionsSpringer \| ISBN: 1402087640 \| 2008-12-01 \| PDF \| 454 pages \| 4 Mb This book describes two main classes of non-equilibrium phase-transitions: (a) static and dynamics of ...
	Science/Engineering Phase Transitions and Critical Phenomena, Volume 19 (Phase Transitions and Critical Phenomena) Cyril Domb "Phase Transitions and Critical Phenomena, Volume 19 (Phase Transitions and Critical Phenomena)"Academic Press \| 2000-09-15 \| ISBN: 0122203194 \| 576 pages \| DJVU \| 5.01 MBThe field of phase transitions and critical phenomena cont ...
	Science/Engineering Kinetics of Phase Transitions Sanjay Puri, Vinod Wadhawan, "Kinetics of Phase Transitions" CRC \| 2009 \| ISBN: 0849390656 \| 346 pages \| PDF \| 14,1 MB Providing a comprehensive introduction with the necessary background material to make it accessible for a wide scientif ...
	Science/Engineering Geometry and Phase Transitions in Colloids and Polymers William Kung, "Geometry and Phase Transitions in Colloids and Polymers" World Scientific Publishing Company \| 2009 \| ISBN: 9812834966 \| 216 pages \| PDF \| 4,4 MB This monograph represents an extension of the author's original PhD thesis an ...
	Metastable States in Amorphous Chalcogenide Semiconductors Victor I. Mikla, Victor V. Mikla "Metastable States in Amorphous Chalcogenide Semiconductors"Springer \| English \| 2009-12-01 \| ISBN: 364202744X \| 122 pages \| PDF \| 2,2 MBThis book addresses an interesting and technologically important class ...

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