Neodymium Based Ziegler Catalysts Fundamental Chemistry APS 204 2006 pdf (3540348092)

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Neodymium Based Ziegler Catalysts - Fundamental Chemistry (Advances in Polymer Science , Vol. 204)

Even though Ziegler catalysts have been known for almost half a century, rare earth metals (Ln), particularly neodymium (Nd)-based Ziegler catalyst systems, only came into the focus of industrial and academic research well after the large scale application of titanium, cobalt and nickel catalyst systems. As a direct consequence of the late recognition of the technological potential of rare earthmetal Ziegler catalysts, these systems have attractedmuch attention. Considerable progress has been made in this field as a result of intensive work performed during the last few years. Worth mentioning is the structural identification of a variety of Ln/Al heterobimetallic complexes and the role of alkyl aluminum cocatalysts in molar mass control. Furthermore, a deeper understanding of the polymerization mechanism, such as the living character of neodymium-catalyzed diene polymerization associated with the reversible transfer of living polymer chains between Nd and Al, was revealed quite recently. In spite of the vast number of patents and publications mainly issued during the last decade, a comprehensive review that covers the scientific aswell as the patent literature has been missing until now. From Preface.

Contents

Neodymium Based Ziegler/Natta Catalysts and their Application in Diene Polymerization

L.Friebe·O.Nuyken·W.Obrecht

Rare-EarthMetals and Aluminum Getting Close in Ziegler-type Organometallics

A.Fischbach·R.Anwander

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