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Ketenes by Thomas T. Tidwell
Posted on 2010-07-17
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More It was a century ago that Hermann Staudinger introduced ketenes to the world, and almost 50 years ago that I first encountered these beguiling reactive intermediates in my first course in organic chemistry, using a textbook written by the inimitable Louis Fieser. Ketenes are remarkable for the variety of ways in which they can be prepared, for their high chemical reactivity, and for the diverse range of useful products from their reactions. Ketenes have long been renown for their unique reactivity in [2+2] cycloaddition reactions giving a ready source of four membered ring compounds, their distinctive characteristic of undergoing facile dimerization, and the high stereoselectivity shown in many of their reactions.
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