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Science/Engineering Free Energy Relationships in Organic and Bioorganic Chemistry

Posted on 2010-03-15




Name:Science/Engineering Free Energy Relationships in Organic and Bioorganic Chemistry
ASIN/ISBN:0854046763
Language:English
File size:14.5 Mb
Pages: 278
Publish Date: 2003-10-17
ISBN: 0854046763
File Size: 14.5 MB
Other Info: Royal Society of Chemistry
   Science/Engineering Free Energy Relationships in Organic and Bioorganic Chemistry

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A. Williams"Free Energy Relationships in Organic and Bioorganic Chemistry"

Introducing the application of free energy correlations to elucidating the mechanisms of organic and bioorganic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for the problems posed. Databases of parameters, an extensive bibliography and comprehensive lists of further reading are also included.

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