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Science/Engineering Electron Spin Resonance Spectroscopy for Organic Radicals By Fabian Gerson, Walter Huber
Posted on 2010-03-15
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More Electron Spin Resonance Spectroscopy for Organic Radicals By Fabian Gerson, Walter Huber Electron spin resonance spectroscopy is the method used to determine the structure and life expectancy of a number of radicals. Written by Fabian Gerson and Walter Huber, top experts in the field of electron spin resonance spectroscopy, this book offers a compact yet readily comprehensible introduction to the modern world of ESR. Thanks to its comprehensive coverage, ranging from fundamental theory left up to the treatment of all important classes of organic radicals and triplet-state molecules that can be analyzed using ESR spectroscopy, this unique book is suitable for users in both research and industry. Instead of using complex mathematical derivations, the authors present a readily understandable approach to the field by interpreting sample spectra and classifying experimental data. In short, the ideal book for newcomers to the subject and an absolute must-have for everyone confronted with ESR spectroscopy and wanting to become acquainted with this widely-used method of analysis. Table of Contents Preface Abbreviations and Symbols A: General Part 1 1 Physical Fundamentals of Electron Spin Resonance 3 2 Paramagnetic Organic Species and Their Generation 10 3 Electron-Nuclear Magnetic Interaction 37 4 Spin Density, Spin Population, Spin Polarization, and Spin Delocalization 49 5 Multiresonance 83 6 Taking and Analyzing ESR Spectra 97 B: Special Part 167 7 Organic Radicals Centered on One, Two, or Three Atoms 169 8 Conjugated Hydrocarbon Radicals 210 9 Conjugated Radicals with Heteroatoms 290 10 Saturated Hydrocarbon Radicals 375 11 Biradicals and Triplet-state Molecules 386 App. A.1 Nitroxyls as Spin Labels and Spin Adducts 405 App. A.2 Hyperfine Splitting by Alkali-Metal Nuclei in Counterions of Radical Anions 409 References 415 Index 447
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