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Chiral Photochemistry

(in series ,,Molecular and Supramolecular Photochemistry'', vol. 11)

edited by Y. Inoue and V. Ramamurthy

Control of molecular chirality is central to contemporary chemistry, biology, and materials-related areas. Chiral photochemistry employs molecular and supramolecular chiral interactions in the electronically excited state to induce molecular chirality, providing new and versatile strategies and surprising results unattainable by conventional thermal asymmetric synthesis. Chiral Photochemistry is the first book devoted solely to this rapidly growing area. This comprehensive and authoritative book covers all aspects of the subject, from circularly polarized light to supramolecular chiral source and from the origin of homochirality in the biosphere to chiral devices and materials.

Table of Contents

1 Direct asymmetric photochemistry with circularly polarized light 1

2 Coherent laser control of the handedness of chiral molecules 45

3 Magnetochiral anisotropy in asymmetric photochemistry 107

4 Enantiodifferentiating photosensitized reactions 129

5 Diastereodifferentiating photoreaction 179

6 Chirality in photochromism 235

7 Chiral photochemistry with transition metal complexes 261

8 Template induced enantioselective photochemical reactions in solution 315

9 Chiral supramolecular photochemistry in solution 341

10 Circular dichroism in the solid state 385

11 Absolute asymmetric photochemistry using spontaneous chiral crystallization 415

12 The solid state ionic chiral auxiliary approach to asymmetric induction in photochemical reactions 463

13 Chiral solid-state photochemistry including supramolecular approaches 485

14 Racemic-to-chiral transformation and the chirality inversion process in cobaloxime crystals only by photoirradiation 533

15 Chiral photochemistry within zeolites 563

16 Photochemistry of chiral polymers 633

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