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Chemistry of Superconductor Materials: Preparation, Chemistry, Characterization and Theory

by: C. W. Gardiner, P. Zoller

This thorough review of the chemistry of highTc superconductors provides extensive coverage of the structural and synthetic solid-state chemistry of oxide supercondustors as well as substantial reference material on characterization methods. Written by 27 authorities in the field, the book fulfills a need for a condensed, single-source reference. It will be indispensable for researchers, and to those unfamiliar with structural and synthetic solid-state chemistry of superconductors.

Contents

PART I

INTRODUCTION

1. HISTORICAL INTRODUCTION AND CRYSTAL CHEMISTRY OF OXIDE SUPERCONDUCTORS

PART II

2. STRUCTURAL AND PREPARATIVE CHEMISTRY

THE COMPLEX CHEMISTRY OF SUPERCONDUCTIVE LAYERED CUPRATES

3. DEFECTIVE STRUCTURES OF Ba2YCu3Ox, AND Ba2YCu3-yMyOz, (M = Fe, Co, AI, Ga, . . .)

4. CRYSTAL CHEMISTRY OF SUPERCONDUCTORS AND RELATED COMPOUNDS

5. CRYSTAL GROWTH AND SOLID STATE SYNTHESIS OF OXIDE SUPERCONDUCTORS

6. PREPARATION OF BISMUTH- AND THALLIUM BASED CUPRATE SUPERCONDUCTORS

7. SYNTHESIS OF SUPERCONDUCTORS THROUGH SOLUTION TECHNIQUES

8. CATIONIC SUBSTITUTIONS IN THE HIGH T, SUPERCONDUCTORS

10. CRYSTAL CHEMISTRY OF SUPERCONDUCTING BISMUTH AND LEAD OXIDE BASED PEROVSKITES

11. STRUCTURE AND CHEMISTRY OF THE ELECTRONDOPED SUPERCONDUCTORS

PART III

SAMPLE CHARACTERIZATION

12. X-RAY IDENTIFICATION AND CHARACTERIZATION OF COMPONENTS IN PHASE DIAGRAM STUDIES

13. STRUCTURAL DETAILS OF THE HIGH T, COPPERBASED SUPERCONDUCTORS

14. CHEMICAL CHARACTERIZATION OF OXIDE SUPERCONDUCTORS BY ANALYTICAL ELECTRON MICROSCOPY

15. ELECTRON MICROSCOPY OF HIGH TEMPERATURE SUPERCONDUCTING OXIDES

16. OXIDATION STATE CHEMICAL ANALYSIS

17. TRANSPORT PHENOMENA IN HIGH TEMPERATURE SUPERCONDUCTORS

18. STATIC MAGNETIC PROPERTIES OF HIGH TEMPERATURE SUPERCONDUCTORS

PART IV

STRUCTURE-PROPERTY CONSIDERATIONS

19. ELECTRONIC STRUCTURE AND VALENCY IN OXIDE SUPERCONDUCTORS

20. ELECTRON-ELECTRON INTERACTIONS AND THE ELECTRONIC STRUCTURE OF COPPER OXIDE BASED SUPERCONDUCTORS

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