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Boronic Acids: Preparation and Applications in Organic Synthesis and Medicine by Dennis G. Hall

For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook.

Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine. Starting with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.

Preface.

List of Authors.

List of Abbreviations.

1 Structure, Properties, and Preparation Of Boronic Acid Derivatives. Overview of Their Reactions and Applications (D. G. Hall).

2 Metal-catalyzed Borylation of Alkanes and Arenes via C–H Activation for Synthesis of Boronic Esters (T. Ishiyama and N. Miyaura).

3 Coupling Reactions of Areneboronic Acids or Esters with Aromatic Electrophiles (A. Suzuki).

4 Rhodium-catalyzed Additions of Boronic Acids to Alkenes and Carbonyl Compounds (K. Yoshida and T. Hayashi).

5 Recent Advances in Copper-promoted C–Heteroatom Bond Cross-coupling Reactions with Boronic Acids and Derivatives (D. M. T. Chan and P. Y. S. Lam).

6 Recent Advances in the Preparation of Allylboronates and Their Use in Tandem Reactions with Carbonyl Compounds (J. W. J. Kennedy and D. G. Hall).

7 Nucleophilic Addition Reactions of Aryl and Alkenylboronic Acids and Their Derivatives to Imines and Iminium Ions (R. A. Batey).

8 (á-Haloalkyl)boronic Esters in Asymmetric Synthesis (D. S. Matteson).

9 Cycloadditions and Other Additions to Alkenyl-, Alkynyl- and Dienyl Boronic Esters (B. Carboni and F. Carreaux).

10 Organoboronic Acids and Organoborinic Acids as Brønsted–Lewis Acid Catalysts in Organic Synthesis (K. Ishihara).

11 Oxazaborolidines as Asymmetric Inducers for the Reduction of Ketones and Ketimines (B. T. Cho).

12 Boronic Acid-based Receptors and Sensors for Saccharides (T. D. James).

13 Biological and Medicinal Applications of Boronic Acids (W. Yang, X. Gao, and B. Wang).

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